Unfortunately as with so many things there is no quick and easy answer Richard and a lot of it comes down to personal preferences.
My own preference is enamel because, as a result of its longer drying time, it is so much more forgiving to apply, either by brush or by airbrush. It is also a harder finish, more resistant to knocks and scratches. The downside is that it dries very hard so, on a very large surface can lead to cracks as a result of the base material flexing over time.
Acrylics can be water based or solvent based, with the solvent based ones probably being a little bit more durable. They are trickier to apply because they dry so fast but the resultant finish is flexible so are much less prone to cracking.
Automotive paints, which used to be mainly cellulose based, tend to now be far more solvent based acrylics. Car body primer in a spray can is actually a very quick, easy and convenient way of getting a really good overall finish that is slightly flexible, good coverage and quick and easy to apply. If you have access to a supplier that can make you a specific colour in a spray can in an automotive paint, I would probably go for that.
Having said that I have just painted a hull in what is known here as 'Coach Enamel', which is a very tough enamel paint. I brushed it on and was really surprised at how easy it was to paint, how well it covered and what a stunning gloss finish it produced. This paint is designed for things like car restoration work and industrial machinery such as traction engines. I might live to regret it if I see cracks after a few years as it is on a wooden hull.
In your case I would go for the automotive paint, it is probably your best bet for getting a good finish on a large area. I would also go for matt or satin as gloss can look too toy like on a model despite the real ship being painted with gloss paint.