1000 mah = 1 ampere hour.
Basicly, it’s a measure of how much power (amps) the battery can hold. If a battery is 2 amp hours (2000mah) capacity, it would run a motor that draws 1 amp current for 2 hours. So, the bigger the capacity, in terms of ah (mah) the longer the motor would run for. A bigger capacity lasts longer.
That answer will do nicely to give you the idea of what the term means, but in reality it’s a bit more complicated. The actual running time for a given current will vary with battery type,and the current drawn as some batteries capacities depend on the actual current taken.
In practice don’t worry too much. If you are getting the running time from your 1000mah battery that you want, you don’t need to upgrade.
To answer your last point, yes you could join them in parralel, BUT I certainly wouldn’t. Any slight difference in the packs will lead to problems very soon as 1 pack will charge / discharge differently to the other. Profesionaly made packs of this type have carefully matched cells.
I hope that helps, if not get back on the forum.
Charlie.