Hi Ian,
The underlying finish probably doesn't matter too much as long as you get a nice smooth result.
Obviously the varnish needs to be the traditional solvent based polyurethane variety and not the quickdry stuff.
That said, I have found that the matt variety gives a slight sheen which I personally find preferable to the satin finish.
The interior variety is fine as it doesn't contain the UV filters which can give a yellowish tint.
I assume you are looking at Ronseal Mattcoat.
Mattcoat
but I have also found the similar Blackfriars polyurethane to go on slightly better.
Blackfriars
Our late lamented Editor, Paul Freshney was an airbrush expert and always used Ronseal Polyurethane over Humbrol Enamel using airbrushes for his award winning models and wrote an article on it for one of my Special issues. You might find this very useful so if you confirm your email to me by personal message I will send you a copy.
Colin
Edited By Colin Bishop on 15/06/2022 18:30:02