Hello Andrew,
As Dave M says, I use a range of acrylic model paints and associated products called Vallejo Premium RC (**LINK**). As would, I am sure, be true for any kind of paint, they have both strong and weak points.
More specifically, they are primarily intended for airbrush application, which is also how I mostly use them. They can certainly be applied with a brush, too, and I have decent experiences of this, too, albeit much more limited than my airbrush useage. They do not come in rattle cans.
With the airbrush, they can be applied straight out of the bottle with any needle size above 0.4, and have splendid covering and self-equalizing properties. From my limited experience of brush application, I would also say that they go on very smoothly that way too, and will self-equalize quite nicely. However, I have never really tried painting any large, flat surface like a hull with a brush, so cannot really review them from that point of view. Based on the smaller and touch-up work that I have done with a brush, however, I would say I think it should be feasible to get a nice result that way also on larger surfaces, if care is taken.
They have a flat white primer paint that is a very good primer, and a gloss white top coat paint that are both nice enough to work with. The pigments in the gloss white are perhaps not quite as strong as those in other colours (their bright red for instance is fantastic, and the black outstanding), and so might require a few more coats for good coverage, but otherwise should be fine. If applied with an airbrush, I have found the primer to be a tad on the sticky side, compared to the top coat paints, with a fairly rigourous cleaning schema required to stop the nozzle from clogging, but then again, sticky is exactly what a primer should be, so that sort of goes with the territory.
I also use the clear polyurethane varnishes in the Premium RC-series, and so far haven't noticed any yellowing, but then again I've yet to paint any such surface as the bottom of a hull all white, so cannot really say one way or the other if there is such a problem with this particular varnish.
These paints are primarily intended for r/c car bodies, and so are not often found in standard model or hobby shops. They are however available from i.a. Amazon; both the white primer (**LINK**) and the gloss white (**LINK**). They are also carried by Everything Airbrush (**LINK**) and even by a Purveyor to HM The Queen (**LINK**)! Further googling would, I'm sure, throw up yet more vendors in and out of the UK.
Two more words of caution, should you decide to give them a try:
1. Always, always, always do a test piece first of the combination of paints and products you intend to use, both to ensure compatibility and (if one component is a new aquaintance) to familiarise yourself with their behaviour.
2. Where solvent-based paints dry from the inside out and thus, when dry to the touch, are basically dry all the way through, acrylics dry from the outside in and thus, while dry to the touch, may still be partially wet underneath, and thus unstable or not yet at full strength, which can lead to nasty surprises when e.g. applying masking tape to a newly painted area. The Vallejo Premkum RC-piants when airbrushed will be dry to a light touch within minutes but, depending on the number coats and their thickness, as well as room temperature and humidity, will only be fully cured after between, say, 48 and 72 hours.
Personally, I very much like these paints — not least, perhaps, because I am now familiar with them and their behaviour — and for someone looking to try summat new or having no established range of favourite paints, I would definitely recommend them for a trial. Whether or not you would like them, I obviously cannot say; the only way to find that out would be to try them for yourself.
Also, if you are lucky enough to have trusty, local hobby store that carries e.g. Humbrols, the convenience of being able to pop in for another tin might argue against the inconvenience of having to send off for paints; if, on the other hand, you would have to do so anyway, well …
Mattias