Hi Paul, it's difficult to be sure from your post whether you are trying to bend a large piece of ply, or just a small piece to make the bulwark from. I prefer to make a template from card when I'm making bulwarks, those compound curves can be tricky. When you have an accurate pattern, use it to cut the ply to shape, making the ply ever so slightly bigger to allow for mistakes. It shouldn't be a problem to bend thin ply, provided the grain is going the correct way. If soaking doesn't do it, try steaming or heat on the wet wood, then slowly coaxing the wood to shape.
Of course, you might just have a dodgy bit of wood, but that's rare.
Chas