If it is the left and right halves, with a long join the length of the hull down the middle, a fillet of polystyrene cement along the length of the join after they have been tacked into place will last as long as the plastic and be just as waterproof. Since it works by dissolving the plastic, allowing it to run together and then drying solid, effectively the two halves become one piece of waterproof plastic. A close mechanical fit is obviously a good thing. You can always add some extra strength (more for confidence than any real need) by sticking a strip of styrene sheet over the gap. From the inside, of course.
If it is a join between two parts that might at some time need separating, sealant by all means, but as stated above, it must not come into contact with any areas that will be painted, because they won't stay painted.