"Why and how are those batteries different to other batteries? Apart from the obvious".
Whoa there, fella! I think you read a bit more than I intended into what I said . Firstly I only mentioned NiCad and NiMH because Mick specifically said he has 7.2v batteries and, as far as I know, you can’t get SLA or LiPo batteries or packs which give that nominal voltage.
As to the "why" and "how", there’s been a lot of debate about this elsewhere so I won’t bore anyone with repeats. It would perhaps have been illuminating for you to have been in my workshop yesterday while I repaired a badly-burned PCB, caused by one battery attempting to charge up a parallel one with less charge in it. The copper land had been blasted off the epoxy-glass board and left a "trench" about 0.2mm deep. THAT’S why I don’t recommend etc etc. The customer didn’t say whether he’d been using SLA or Nickel-based batteries, but either type will do the same sort of damage under similar circumstances. Ref my presentation, I have to say that there’s a world of difference between a bald "you must not" and a mild "I wouldn’t recommend". I usually finish off my posts with either "Works for Me" or "Suit yourself"; maybe I should be more careful to do so on this Forum.
Finally I was conscious of Mick’s statement about not being technical. Granted there is a time-honoured method of using microswitches to reverse the polarity of a motor at extreme rudder. The downside of this is that it’s very fierce and that it only happens at full rudder. Maybe you could point out a suitable link where Mick and others could find such a circuit; that way he/they can make a more informed choice?
I’m afraid I don’t understand your last paragraph in the context of controlling twin motors. If I read it correctly one stops the boat and applies full rudder and full trim, then proceeds with one motor in full reverse………?? Who’s to say? Maybe it works for you.