Hello Phil,
I do not wish to disparage in any way rattle can paints or discourage you from using them; I have very little personal experience of these anyway. Obviously and as always, Paul T is spot on when he says that one should first test any unkown or doubtful combinations of surface treatments on a piece of scrap before applying them to a model.
However, as you mentioned that you might at some point be interested in trying out spray gun application of "a modern paint system", I just wanted to say that I have been very happy indeed with the Vallejo Premium RC Color (**LINK**) range of acrylic polyurethane paints. These are primarily intended for r/c car bodies, and are thus tougher and more resilient than most other acrylic model paints. The pigments are fabulous, with an extremely good coverage, and the paints are equally suited to brush and airbrush application.
Being acrylic, no solvents are involved, so while not odorless they are completely pong free (if you spray them on, though, even with acrylics always wear a good half mask to avoid breathing in miniscule particles of paint).
The range of colours is much more limited than e.g. Humbrols, but they are eminently suited to mixing, and I have made up a number of shades to suit my needs.
I have gotten equally good results on GRP, styrene, metals and woods.
On the disadvantage side, like all acrylics they dry from the outside in, so although they will be dry to the touch within 15 to 30 minutes, real and thorough curing of in particular larger surfaces can, depending on conditions, take several days. Although a previous coat can be oversprayed within hours, I would usually not attempt e.g. masking off before the paint had been left to cure for at least 48 hours.
They are rather less easy to find than many other model paints, so should anyone wish to try them out, they would probably have to order them online. One webshop in the UK that I know carries them is Model Hobbies: **LINK** who by the way also sells these paints through Amazon UK.
Again, I am in no way trying to dissuade you from using spray cans, but just wanted to mention this in my view rather excellent range of paints.
/Mattias